The product formed when ethanol reacts with ethanoic acid in presence of concentrated H₂SO₄ is: MCQ with Answer and Explanation

The product formed when ethanol reacts with ethanoic acid in presence of concentrated H₂SO₄ is:
A. Ethyl ethanoate
B. Ethane
C. Ethene
D. Methanol
Answer: Option A
Solution (By JKSSB Mock Tests)
C₂H₅OH + CH₃COOH ⇌ CH₃COOC₂H₅ + H₂O (esterification). Conc. H₂SO₄ acts as catalyst and dehydrating agent. Ethyl ethanoate is an ester with fruity smell.

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Question #1
Vanadium(V) oxide is used as a catalyst in the manufacture of:
A. Sodium hydroxide
B. Sulphuric acid
C. Ammonia
D. Nitric acid

Correct Answer: Option B


Explanation:
V₂O₅ catalyzes the oxidation of SO₂ to SO₃ in the Contact process for sulfuric acid: 2SO₂ + O₂ ⇌ 2SO₃. Fe is used for ammonia (Haber). Pt-Rh gauze for nitric acid (Ostwald). Sodium hydroxide is made by chlor-alkali electrolysis, no catalyst needed. V₂O₅ is preferred over Pt because it is cheaper and less susceptible to poisoning by arsenic impurities.

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Question #2
The setting of plaster of Paris involves:
A. Hydration to form gypsum
B. Oxidation
C. Dehydration
D. Carbonation

Correct Answer: Option A


Explanation:
Plaster of Paris (CaSO₄·½H₂O) sets by rehydrating to gypsum (CaSO₄·2H₂O) when mixed with water: CaSO₄·½H₂O + 1½H₂O → CaSO₄·2H₂O. The interlocking crystals of gypsum provide hardness. It expands slightly on setting, making it ideal for casting. Dehydration is the opposite. Oxidation and carbonation are not involved.

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Question #3
Which of the following is an example of a strong base?
A. Mg(OH)₂
B. NH₄OH
C. NaOH
D. Ca(OH)₂ (slightly soluble)

Correct Answer: Option C


Explanation:
NaOH is a strong base, fully dissociating into Na⁺ and OH⁻ ions. NH₄OH is a weak base. Ca(OH)₂ and Mg(OH)₂ are sparingly soluble but are considered strong bases in terms of dissociation of dissolved portion, but NaOH is the strongest among common ones.

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