In the reaction 2SO₂ + O₂ → 2SO₃, the type of reaction is:
A. Decomposition
B. Neutralization
C. Displacement
D. Combination
Answer: Option D
Solution (By JKSSB Mock Tests)
Two or more substances (SO₂ and O₂) combine to form a single product (SO₃). This is a combination reaction. It is also a redox reaction and is catalyzed by V₂O₅ in the Contact process for sulfuric acid. Decomposition is the opposite (breaking down). Displacement involves replacement of an element.
Explanation:
Graham's law: Rate of diffusion/effusion ∝ 1/√M, where M is molar mass. Lighter gases diffuse faster. At same T and P, rates of two gases r₁/r₂ = √(M₂/M₁). Example: NH₃ (17 g/mol) diffuses faster than HCl (36.5 g/mol). This law is used in isotope separation (e.g., ²³⁵UF₆ vs ²³⁸UF₆). The law assumes no intermolecular forces and identical conditions.
Explanation:
Calorific value is determined using a bomb calorimeter, where a known mass of fuel is burnt in excess oxygen in a sealed bomb, and the heat released is absorbed by a known mass of water. Temperature rise is measured. Corrections for cooling, wire, and acid formation are applied. Units: kJ/kg or kJ/mol. The bomb calorimeter works at constant volume.
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