Assertion (A): A catalyst does not change the equilibrium yield of a reaction. Reason (R): A catalyst speeds up both the forward and backward reactions equally. MCQ with Answer and Explanation
Assertion (A): A catalyst does not change the equilibrium yield of a reaction. Reason (R): A catalyst speeds up both the forward and backward reactions equally.
A. Both A and R are true and R is the correct explanation of A.
B. Both A and R are true but R is NOT the correct explanation of A.
C. A is true but R is false.
D. A is false but R is true.
Answer: Option A
Solution (By JKSSB Mock Tests)
A catalyst lowers the activation energy for both the forward and reverse reactions by the same amount. Therefore, it increases the rates of both reactions equally, allowing the system to reach equilibrium faster, but without changing the final equilibrium concentrations (yield). Both statements are correct and R explains A.
Explanation:
Diammonium phosphate (DAP) is (NH₄)₂HPO₄. It is produced by reacting ammonia with phosphoric acid: 2NH₃ + H₃PO₄ → (NH₄)₂HPO₄. It contains 18% N and 46% P₂O₅. Monoammonium phosphate (MAP) is NH₄H₂PO₄. Ammonium sulfate is (NH₄)₂SO₄. Triammonium phosphate is unstable. DAP is widely used as a starter fertilizer.
Explanation:
Oleum, also known as fuming sulfuric acid, is a solution of sulfur trioxide (SO3) in concentrated sulfuric acid (H2SO4). Its chemical formula is often represented as H2S2O7 (disulfuric acid or pyrosulfuric acid), which is essentially H2SO4 + SO3. It is an intermediate in the Contact process.
Explanation:
Isoelectronic species have the same total number of electrons. Carbon monoxide (CO) has 6 (from C) + 8 (from O) = 14 electrons. Nitrogen molecule (N2) has 7 + 7 = 14 electrons. Therefore, N2 is isoelectronic with CO. O2 has 16, CO2 has 22, and NO has 15 electrons.
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