During the extraction of aluminium by Hall-Héroult process, cryolite (Na₃AlF₆) is added to alumina to: MCQ with Answer and Explanation

During the extraction of aluminium by Hall-Héroult process, cryolite (Na₃AlF₆) is added to alumina to:
A. Lower the melting point and increase conductivity
B. Act as catalyst
C. Increase the yield of aluminium
D. Prevent corrosion
Answer: Option A
Solution (By JKSSB Mock Tests)
Alumina has a very high melting point (~2050°C). Cryolite (and fluorspar) is mixed to form a molten mixture with lower melting point (~950°C) and better electrical conductivity, enabling electrolytic reduction. The electrolyte is a solution of alumina in molten cryolite. Carbon anodes are consumed. This reduces energy consumption.

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